I've read this thread a number of times today, also DeeDeeK's threads and several others on the net.
A couple of thoughts,
If O2 is reducing and CO2 increasing that would indicate too many things using the O2, you have said above that you have a lot of snails, maybe a cull of these would help.
Also the DBF is also producing CO2, this area of the filter could be running too efficiently (no idea how you could reduce this)
How long do you have the lights on? plants use CO2 in daylight and O2 in low light levels.
Turning the air pump on and off could also be counter productive. With no water agitation, partial pressures and thermal currents will set up in the tank - obviously aided by the fish movements - plants will obstruct this flow. Turning on the pump will then change all this and it will take time for new flow pattens to establish - the more obstructions in the tank the longer it will take for this flow pattens to establish.
From memory (it's been a very long time since I did chemistry at school) sulhpur compounds tend to be acidic, therefore shells in the substrate will act as a Ph buffer, something I really need to look at for my filter as it'll be for a cichlid tank which needs around 8-8.5 Ph
A couple of thoughts,
If O2 is reducing and CO2 increasing that would indicate too many things using the O2, you have said above that you have a lot of snails, maybe a cull of these would help.
Also the DBF is also producing CO2, this area of the filter could be running too efficiently (no idea how you could reduce this)
How long do you have the lights on? plants use CO2 in daylight and O2 in low light levels.
Turning the air pump on and off could also be counter productive. With no water agitation, partial pressures and thermal currents will set up in the tank - obviously aided by the fish movements - plants will obstruct this flow. Turning on the pump will then change all this and it will take time for new flow pattens to establish - the more obstructions in the tank the longer it will take for this flow pattens to establish.
From memory (it's been a very long time since I did chemistry at school) sulhpur compounds tend to be acidic, therefore shells in the substrate will act as a Ph buffer, something I really need to look at for my filter as it'll be for a cichlid tank which needs around 8-8.5 Ph