Again thanks for the help, My tank No3 seems to linger around 80ppm that wasn't a typo, My tap is at 40ppm and it just seems to go up once it hits the tank? I was running an air stone at night figuring precipitating the Co2 out at night would help the plants, by allowing more O2 uptake. The flip side of that is what you had mentioned that it takes too long to reach appropriate Co2 levels in the morning. I think it is also allowing to much residual O2 with the powerful lighting for the algae to thrive-in in the morning. I stopped that about 2 days ago. What I was saying was that I was trying to get to a 10:1 ratio but have not been able to get there yet. I thought it would be better to bring the No3 into ratio with the Po4, (but find it hard when the tap is at 40 ppm it is probably easier to bring the Po4 up instead) Is 1ppm Po4 the recommended amount? I am very afraid of raising my Po4, although I know it is probably the right thing to do! . I have sodium biphosphate do you think that would work to raise the Po4? I will try anything twice.