The fish gasping is surprising, your plants should be producing plenty of O2, although if your CO2 levels are still high this could cause the problem. I don't know about fish, but our brains don't actually detect blood O2, they detect blood CO2 and we feel short of breath when blood CO2 levels rise, regardless of O2 levels. If fish are the same then even with ample O2 in the water, CO2 levels much higher than 30ppm may be causing them to gasp, that said, since I'm on DIY, I've had short periods when CO2 reached the low 50's and observed no problems, but I think that I was just lucky and since it wasn't prolonged, no problems.
Now, to your question:
CO2 isn't dissipating at any higher rate at night than in the day. Presumably you have the same amount of surface agitation around the clock. Plus, at night there's no heat on the surface water to help speed dissipation, but I don't know how significant that it. Okay, so part one is that the loss from the surface is the same at night as during the day.
Next, while you are no longer providing CO2 at night, the plants are no longer using it, so both source of CO2 to the water and loss to the plants kind of balance each other to some extent.
Finally, at night, plants respire, so at night your plants switch from consuming CO2 and producing O2 to consuming O2 and producing CO2. Your fish continue to respire as they did throughout the day. So at night you still have a net production of CO2, hence your decreasing pH.
Normally this wouldn't be significant, but I suspect that since your CO2 levels have been up around 70ppm that they're struggling to come back down. The easiest way to set it right is to do a water change to reset your CO2 levels and then set your setup so that you have about 30ppm of CO2 when the lights first come on, but allow your CO2 level to fall to about 25ppm when the lights switch off. I've never used a setup like the one you describe, but it should be fairly simple to initiate. I gotta run right now, I can elaborate in a pm a little later if you like.