Forgot to hit post reply last night.
An animal is venomous if it has a delivery system in which the toxin is delivered directly into the body of the prey or predatory animal. So snakes and spiders have fangs, bees and other inverts have a stinger, there are grooves in a shrew's teeth, and a lot of fish (stonefish, scorpion fish, some catfish, etc.) have spines that deliver the toxin directly into the body of the prey or predatory animal.
A poisonous animal, on the other hand, does not have a delivery system and the toxin is delivered passively when a predator ingests or touches the poisonous animal. So dart frogs and a quite a few other amphibians, pufferfish, a lot of caterpillars and insects, and I'm sure others that just aren't coming to mind right now, are poisonous.
I'm not sure where animals like skunks and some insects that spray their toxin fall. They have a delivery system but don't inject it into the body. And yes, skunk spray is toxic to humans at very high concentrations.
The toxin of a poisonous animal doesn't have to be fatal, and often isn't. It just has to make the predatory animal sick and invoke an avoidance response so the predator avoids individuals of that species in the future. Toxins of venomous species, however, are often (but not always) used to immobilize or kill prey animals as well as for defense, and therefore are more likely to be deadly. Snakes, spiders, and scorpions use their venom for hunting, but the spines of most fish are purely defensive. Batesian mimicry is when a harmless species mimics the appearance of a dangerous species so that it benefits from the avoidance response the dangerous species elicits. It's common in invertebrates but not so much in vertebrates. There are examples among butterflies, bees, flies and who knows how many other invertebrates. One well known example among vertebrates is non-venomous kingsnakes mimicking venomous coral snakes. I'm sure a lot of us have heard the rhyme, "Red touch yellow, kill a fellow," to discern between the two. That only works in North American species, though.
So I don't think there is any amphibian that has a mechanism to deliver the toxin directly, so they are poisonous. And not all amphibians are poisonous, so you probably have absolutely nothing to worry about.
WYite