There is all the difference in the world between a saturated solution of anything in distilled and in tank water. Putting out on the aquarium forums that Ca++ affects pH is not only misleading and confusing to folks w/o chemistry backgrounds, it is, in terms of the subject under discussion, absloutely wrong. Anybody who says that is not helping, they are hurting hobby understanding of GH and KH. I will never hesitate to call anyone on that.
In this hobby, high GH = hard water. If it is natural water, mostly it will be high in carbonates/bicarbnoates as well, but the high pH is due to the carbonates/bicarbonates, not to the anions* to which they were associated before the minerals went into solution. In processed water, all bets are off, depending on the processes involved and the additives used.
*Edit: Well, I blew that one and nobody caught it...it should have said cations.
Cations are not hyperactive felines, they are positively charged ions, i.e., Na+, K+, Ca++, Mg++, etc.. Anions are not necessarily hot dog toppings, they are negative charged ions, i.e. Cl-, NO3-, SO4--, CO3--, HCO3-, etc.. Does that help or make it worse?