For a planted tank, this will not reduce your power bill. Compared to a T5 or T12 bulb, in order to achieve the same light level in the tank, using CFL's will actually increase your power bill. If you use the same amount of watts, since the efficiency of CFL's is decreased compared to T5s and T12s, you have to actually add more bulbs to maintain the same amount of useable light. I run 206 watts of CFL, but it's really only about 170 watts of useable light. I did that because it was cheaper up front. In the long run, an AH supply retrokit probably would have paid itself off just in terms of effciency(especially out here in Cali).
100 watts is 100 watts, no matter what kind of bulbs they are.
Even an incadescent hood still has a 20 watt bulb. If you replace it with a 20 watt CFL, your tank may get brighter and you'll be able to grow plants, but it'll still be 20 watts on your power bill. Almost everybody has fluorescents in aquariums now(unless you are using metal halides), so CFL vs T5, watts is watts.